Insights on Adsorption Characterization of Metal-Organic Frameworks: A Benchmark Study on the Novel soc-MOF

نویسندگان

  • J. Moellmer
  • E. B. Celer
  • R. Luebke
  • A. J. Cairns
  • R. Staudt
  • M. Eddaoudi
  • M. Thommes
چکیده

Please cite this article in press as: J. Moellmer e In order to explore the potential of novel open metal organic frameworks (MOFs) with soc topology for gas storage applications, we performed a systematic physical adsorption study with Hydrogen, Methane and Carbon dioxide as adsorptives over a wide range of temperatures (77–323 K) and pressures (0– 5 MPa) by using a volumetric low pressure adsorption analyzer equipped with a cryostat, and a high pressure gravimetric system. The advanced interpretation of our systematic adsorption data in combination with the results from a comprehensive structural and surface characterization allows one assessing the potential of these novel MOFs for gas storage and separation applications. 2009 Elsevier Inc. All rights reserved.

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تاریخ انتشار 2009